Download PDF by Samuel Glasstone: An introduction to electrochemistry

By Samuel Glasstone

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For precision work it is necessary, however, to consider the problem For alternating current, Ohm's law takes the form in further detail. , Z 2 is equal to 2 /j>2 _|_ x the quantities R and X being the resistance and reactance, The condition for balance of a Wheatstone bridge circuit respectively. C. bridge, at balance. , for RijRi to be equal to R^jR*, at the same time as Zi/Z 2 is equal to Z^/Z^ it is necessary that ances, are balanced. C\ circuit is equal to tan 0, phase angle between the voltage and current in the given conductor.

Has been used particularly for accurate determination of the conductances series of solutions of different concentrations, cell . of a series of dilute solutions of strong electrolytes. Temperature Control. 01. The use of water in the thermostat is not recommended; this liquid has an appreciable conductance and there is consequently a danger of current leakage leading to errors in the measurement, as explained below. The thermostatic liquid should, therefore, be a hydrocarbon oil which is a non-conductor.

174 cc. , assuming the gases to behave ideally. , in electricity meters. 9 The form of apparatus used is shown in Fig. 5; the anode consists of an annular ring of mercury (A) surrounding the carbon cathode (C); the electrolyte is a solution of mercuric iodide in potassium iodide. The mercury liberated at the cathode falls off, under the influence of gravity, and is collected in the graduated tube D. From the height of the mercury in this tube the quantity of electricity passed may be read off directly.

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An introduction to electrochemistry by Samuel Glasstone


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